题目：Engineering ZnIn₂S₄with efficient charge separation and utilization for synergistic accelerate dual-function photocatalysis

作者：Zisheng Du, ChanGuo,MingchunGuo, Sugang Meng^*,Yang Yang,Zhiruo Yu,Xiuzhen Zheng,Sujuan Zhang,ChengChen^*,Shifu Chen^*

单位：Key Laboratory of Green and Precise Synthetic Chemistry andApplications, Ministry of Education,College of Chemistry and Materials Science, Huaibei Normal University, Huaibei, 235000,China.

摘要：Combiningphotocatalyticreduction with organic synthetic oxidation in the same photocatalytic redox system can effectivelyutilize photoexcited electrons and holesfrom solar to chemical energy. Here,we stabilized0DAuclusterson the substrate surfaceof Znvacanciesmodified2DZnIn₂S₄(ZIS-V)nanosheetsbychemically bonding Au-S interaction, forming surfactant functionalized Au/ZIS-V photocatalyst, whichcannot only synergisticacceleratethe selective oxidation ofphenylcarbinol to value-added productscoupled with clean energy hydrogen production but also further drive photocatalyticCO₂-to-CO conversion. An internal electric fieldofAu/ZIS-Vohmic junction and Zn vacanciessynchronouslypromote thephotoexcitedcharge carrier separationandtransfer to optimizedactive sites for redox reactions.Compared with CO₂reduction in water and thepristineZnIn₂S₄,the reactionthermodynamicsandkineticsof CO₂reduction over the Au/ZIS-V were simultaneously improved about 11.09 and 45.51 times, respectively.Moreover, the photocatalytic redox mechanisms were also profoundly studied by¹³CO₂isotope tracing tests,in situ electron paramagneticresonance (in situ EPR), in situX-ray photoelectronspectroscopy (in situXPS),in situ diffusereflection infrared Fourier transform spectroscopy (in situ DRIFTS)anddensity functional theory (DFT) characterizations, etc.These results demonstrate the advantagesofvacancies coupled withmetalclustersinthesynergetic enhancementofphotocatalyticredoxperformance and have great potential applications in awide range of environments and energy.

影响因子：9.4

分区情况：一区

链接：https://authors.elsevier.com/a/1jcZv4-sDf7HUhttps://doi.org/10.1016/j.jcis.2024.08.095

（文：孟苏刚 / 审核：李洪基 / 审校：韩满意 / 终审：韩满意）